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Application of the hammett-taft principle to ascertain the relation between the acidity and the electronegativity of a metal

Conclusions

The extent to which the induction effect affects the complexing of metals with carbonyl compounds is linearly dependent on the electronegativity of the metal.

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Literature cited

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    M. G. Bezrukov, V. B. Bondarev, E. A. Paskonova, and S. V. Vitt, Izv. Akad. Nauk SSSR, Ser. Khim., 342 (1971).

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    E. Gil-Av and J. Herling, J. Phys. Chem.,66, 1208 (1968).

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    S. V. Vitt, E. A. Paskonova, M. G. Bezrukov, and V. B. Bondarev, Izv. Akad. Nauk SSSR, Ser. Khim., 1712 (1971).

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    K. Tanaka and A. Ozaki, Bull. Chem. Soc. Japan,4, 1728 (1967).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2070–2072, September, 1971.

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Bezrukov, M.G., Bondarev, V.B., Paskonova, E.A. et al. Application of the hammett-taft principle to ascertain the relation between the acidity and the electronegativity of a metal. Russ Chem Bull 20, 1959–1960 (1971). https://doi.org/10.1007/BF00854434

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Keywords

  • Acidity
  • Carbonyl
  • Carbonyl Compound
  • Induction Effect