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Electrochemically generated free radicals

Communication 6. Mechanism of the reduction of certain organophosphorus compounds and EPR spectra of the anion radicals formed

Conclusions

  1. 1.

    The mechanism of the electrochemical reduction of certain organophosphorus compounds was studied by a complex of methods.

  2. 2.

    The EPR method was used to study the electrochemically generated anion radicals of triphenyl, its oxide, and the diethyl ester ofβ-styrylphosphonic acid.

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Literature cited

  1. 1.

    M. W. Hanna, J. Chem. Phys.,37, 685 (1962).

  2. 2.

    M. I. Kabachnik, Tetrahedron,20, 655 (1964).

  3. 3.

    M. I. Kabachnik, V. V. Voevodskii, T. A. Mastryukova, S. P. Solodovnikov, and T. A. Melent'eva, Zh. Obshch. Khim.,34, 3234 (1964).

  4. 4.

    A. D. Britt and E. T. Kaiser, J. Phys. Chem.,69, 2775 (1965).

  5. 5.

    A. H. Cowley and M. H. Hnoosh, J. Amer. Chem. Soc.,88, 2595 (1966).

  6. 6.

    V. K. Dimitroth and F. W. Streuber, Angew Chemie,79, 410 (1967).

  7. 7.

    A. V. Il'yasov, Yu. M. Kargin, Ya. A. Levin, I. D. Morozova, N. N. Sotnikova, V. Kh. Ivanova, and N. I. Bessolitsyna, Izv. Akad. Nauk SSSR, Ser. Khim., 740 (1968).

  8. 8.

    Ya. A. Levin, Yu. M. Kargin, V. S. Galeev, and V. I. Sannikova, Izv. Akad. Nauk SSSR, Ser. Khim., 411 (1968).

  9. 9.

    B. V. Mel'nikov, A. V. Il'yasov, Yu. M. Kargin, Ya. A. Levin, V. S. Galeev, Materials of Reports at the Scientific Conference of A. E. Arbuzov, Institute of Organic and Physical Chemistry of the Academy of Sciences of the USSR [in Russian], Kazan' (1969).

  10. 10.

    S. Wawzonek and J. H. Wagenknecht, Polarography, 1964, Vol. 2, Macmillan, London (1966), p. 1035.

  11. 11.

    R. E. Dessy, J. Amer. Chem. Soc.,88, 467 (1966): R. E. Dessy and R. H. Pohi, J. Amer. Chem. Soc.,90, 1995 (1968).

  12. 12.

    K. S. W. Santhanam and A. J. Bard, J. Amer. Chem. Soc.,90, 1118 (1968).

  13. 13.

    A. V. Il'yasov, Yu. M. Kargin, Ya. I. Levin, B. V. Mel'nikov, and V. S. Galeev, Izv. Akad. Nauk SSSR, Ser. Khim., 2841 (1968).

  14. 14.

    A. V. Il'yasov, Yu. M. Kargin, Ya. A. Levin, I. D. Morozova, N. N. Sotnikova, V. Kh. Ivanova, and R. T. Safin, Izv. Akad. Nauk SSSR, Ser. Khim., 736 (1968).

  15. 15.

    Yu. M. Kargin, V. Z. Kondranina, and N. I. Semakhina, Izv. Akad. Nauk SSSR, Ser. Khim., 286 (1971).

  16. 16.

    A. V. Il'yasov, Yu. M. Kargin, N. N. Sotnikova, V. Z. Kondranina, B. V. Mel'nikov, and A. A. Vafina, Izv. Akad. Nauk SSSR, Ser. Khim., No. 5 (1971).

  17. 17.

    Yu. M. Kargin, N. I. Semakhina, B. D. Chernokal'skii, A. S. Gel'fond, and G. Kh. Kamai, Izv. Akad. Nauk SSSR, Ser. Khim., 2488 (1970).

  18. 18.

    A. V. Il'yasov, Yu. M. Kargin. Ya. A. Levin, and B. V. Mel'nikov, Izv. Akad. Nauk SSSR, Ser. Khim., 1979 (1970).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 770–776, April, 1971.

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Il'yasov, A.V., Kargin, Y.M., Levin, Y.A. et al. Electrochemically generated free radicals. Russ Chem Bull 20, 689–694 (1971). https://doi.org/10.1007/BF00853900

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Keywords

  • Oxide
  • Ester
  • Free Radical
  • Diethyl
  • Anion Radical