The conditions of stereospecific polymerization of simple vinyl ethers at room temperature under the influence of a catalyst produced from VOCl3, LiC3H7, and Al(i-C4H39)3 were found.
This system proved especially effective for the polymerization of vinyl n-butyl ether, from which polymers were obtained with molecular weights up to 1.46·106.
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M. F. Shostakovskii, A. V. Bogdanova, A. V. Golovin, and S. Shamakhmudova, Izv. AN SSSR, Otd. khim, n., 1962, 1813.
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M. F. Shostakovskii, Simple Vinyl Ethers [in Russian], Moscow (1952), p, 31.
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Shostakovskii, M.F., Bogdanova, A.V. & Shamakhmudova, S. High-molecular polymers of vinyl n-butyl ether. Russ Chem Bull 13, 334–335 (1964). https://doi.org/10.1007/BF00853698
- Molecular Weight