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Reaction of vinyl ethers and vinyl sulfides with triethyl trithioorthoformate

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Summary

  1. 1.

    A study was made of the reaction of vinyl ethers and vinyl sulfides with triethyl trithioorthoformate in presence of BF3 etherate; it leads to the formation of dimercaptals and mercaptal acetals of malonaldehyde.

  2. 2.

    A method is proposed for the synthesis of malonaldehyde bis[diethyl mercaptal] from ethyl vinyl sulfide or a vinyl ether and triethyl trithioorthoformate in presence of BF3 etherate.

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This article is published in accordance with a resolution of the Conference of Chief Editors of Journals of the Academy of Sciences of the USSR, July 12, 1962, as a dissertation paper by A. N. Dolgikh.

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Dolgikh, A.N., Bogdanova, A.V. & Shostakovskii, M.F. Reaction of vinyl ethers and vinyl sulfides with triethyl trithioorthoformate. Russ Chem Bull 13, 312–314 (1964). https://doi.org/10.1007/BF00853692

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Keywords

  • Acetal
  • Ether
  • Ethyl
  • Sulfide
  • Vinyl