bis(Triethylgermyl)mercury and compounds of the (C2H5)3SnX series, where X=Cl, NCO, OCOCH3, OCH3, N(C2H5)2, CH2COOCH3, enter into the reaction of exchanging the X substituents by (C2H5)3Ge radicals, with the formation of triethylstannyltriethylgermane, mercury and (C2H5)3GeX. The reaction proceeds with the intermediate formation of derivatives containing the Ge-Hg-X group.
The exchange reactions of diethyldichlorostannane and diethyldimethoxystannane with bis(triethylgermyl) mercury proceed by an analogous scheme.
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Kruglaya, O.A., Petrov, B.I., Bortnikov, G.N. et al. Exchange reactions of bis(triethylgermyl)mercury with organotin halides and related compounds. Russ Chem Bull 20, 2118–2121 (1971). https://doi.org/10.1007/BF00851262
- Exchange Reaction
- Related Compound
- Intermediate Formation