3-Fluoro-3, 3-dinitro-1-aminopropane condenses with CH2O and 1,1-dinitroalkanes to form Mannich bases which are readily converted to the corresponding N-nitro- and N-nitroso derivatives.
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L.T.Eremenko, R.G.Gafurov, A.G.Korepin, D.A.Nesterenko, and N.S.Natsibullina, Izv.Akad.Nauk SSSR, Ser.Khim., 1865 (1969).
L.T.Eremenko, R.G.Gafurov, D.A.Nesterenko, A.G.Korepin, and N.S.Natsibullina, Izv.Akad.Nauk SSSR, Ser.Khim., 2562 (1969).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1876–1877, August, 1972.
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Gafurov, R.G., Korepin, A.G., Sogomonyan, E.M. et al. 3-Fluoro-3,3-dinitro-1-aminopropane in the mannich reaction. Russ Chem Bull 21, 1823–1824 (1972). https://doi.org/10.1007/BF00851216
- Mannich Reaction
- Mannich Base