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3-Fluoro-3,3-dinitro-1-aminopropane in the mannich reaction

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Conclusions

3-Fluoro-3, 3-dinitro-1-aminopropane condenses with CH2O and 1,1-dinitroalkanes to form Mannich bases which are readily converted to the corresponding N-nitro- and N-nitroso derivatives.

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Literature cited

  1. 1.

    L.T.Eremenko, R.G.Gafurov, A.G.Korepin, D.A.Nesterenko, and N.S.Natsibullina, Izv.Akad.Nauk SSSR, Ser.Khim., 1865 (1969).

  2. 2.

    L.T.Eremenko, R.G.Gafurov, D.A.Nesterenko, A.G.Korepin, and N.S.Natsibullina, Izv.Akad.Nauk SSSR, Ser.Khim., 2562 (1969).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1876–1877, August, 1972.

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Gafurov, R.G., Korepin, A.G., Sogomonyan, E.M. et al. 3-Fluoro-3,3-dinitro-1-aminopropane in the mannich reaction. Russ Chem Bull 21, 1823–1824 (1972). https://doi.org/10.1007/BF00851216

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Keywords

  • CH2O
  • Mannich Reaction
  • Mannich Base