The phosphorylation of polyfluoroalkanols with the acid chlorides of alkyl- or arylphosphonic acids is catalyzed by group II metal salts.
A number of polyfluoroalkyl esters of alkyl- and arylphosphonic acids were obtained by the catalytic phosphorylation of polyfluoroalkanols.
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Kabachnik, M.I., Godovikov, N.N., Pisarenko, V.V. et al. Preparation of polyfluoroalkyl esters of alkyl- and arylphosphonic acids. Russ Chem Bull 21, 1617–1618 (1972). https://doi.org/10.1007/BF00850539
- Metal Salt
- Acid Chloride
- Catalytic Phosphorylation