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New method for the synthesis of σ-β-ketovinyl derivatives of cyclopentadienyliron dicarbonyl

Conclusions

A new method was developed for the synthesis of σ-RCOCH=CHFe(CO)2C5H5-π by the reaction ofβ-iodovinyl ketones with [Fe(CO)2C5H5-π]2. In this case it was demonstrated for the first time that the reaction of organic haloderivatives with [Fe(CO)2C5H5-π]2 can be used for the synthesis of σ-RFe(CO)2C5H5-σ.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1646–1647, July, 1972.

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Nesmeyanov, A.N., Rybinskaya, M.I., Petrovskaya, E.A. et al. New method for the synthesis of σ-β-ketovinyl derivatives of cyclopentadienyliron dicarbonyl. Russ Chem Bull 21, 1588–1589 (1972). https://doi.org/10.1007/BF00850527

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Keywords

  • Ketone
  • Dicarbonyl
  • Cyclopentadienyliron