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Kinetics of the homolytic interaction of methallyl chloride with CCl4 and steric effects in theβ-elimination of the chlorine atom

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Conclusions

  1. 1.

    The general kinetics of the interaction of methallyl chloride with CCl4 in the presence of azobisisobutyrodinitrile was studied at 55, 75, and 95°.

  2. 2.

    The mechanism of the process was considered, and it was hypothesized that certain differences in the reactivity of the intermediate radicals with respect to bimolecular chain transfer and propagation orβ-elimination of a chlorine atom are determined by the long-range steric interactions of the substituents in the transition states of the corresponding reactions.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1517–1523, July, 1972.

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Englin, B.A., Ismailov, R.D. & Freidlina, R.K. Kinetics of the homolytic interaction of methallyl chloride with CCl4 and steric effects in theβ-elimination of the chlorine atom. Russ Chem Bull 21, 1464–1469 (1972). https://doi.org/10.1007/BF00850496

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Keywords

  • Chloride
  • Chlorine
  • Transition State
  • CCl4
  • Chlorine Atom