In the diffusion approximation, the article discusses the kinetics of the process of deactivation of the vibrations of radiating anharmonic and harmonic oscillators in an inert gas medium. Limiting solutions are given for the purely radiational deactivation of a classical Morse oscillator and of a harmonic oscillator. It is shown that, with an increase in the effect of spontaneous radiation, the role of the anharmonic character of the vibrations in the process of deactivation increases; the initial (or arbitrary) distribution relaxes more slowly the higher its energy level, i.e., the greater the effect of the anharmonic character of the vibrations. The results are of importance for systems with a considerable population of the upper vibrational levels of the molecules, which may arise as a result of a chemical reaction or by the optical pumping of a gas.
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Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 4, pp. 62–67, July–August, 1972.
The author thanks N. N. Magretova for carrying out the numerical calculation.
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Safaryan, M.H. Kinetics of the deactivation of the vibrations of highly excited oscillators in an inert gas medium, taking account of spontaneous radiation. J Appl Mech Tech Phys 13, 484–488 (1972). https://doi.org/10.1007/BF00850389
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