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Influence of oxygen-containing additives on the mechanism of the reaction of benzylmercury chloride with bromine in carbon tetrachloride

Summary

  1. 1.

    The kinetics of the reaction of benzylmercury chloride with bromine in CCl4 in the presence of various oxygen-containing compounds has been studied.

  2. 2.

    The velocity constant of the second-order reaction depends linearly on the dielectric permeability for compounds belonging to a single homologous series.

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Literature cited

  1. 1.

    I. P. Beletskaya, T. A. Azizyan, and O. A. Reutov, Izv. AN SSSR, Otd. khim. n.,1962, 223.

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Beletskaya, I.P., Azizyan, T.A. & Reutov, O.A. Influence of oxygen-containing additives on the mechanism of the reaction of benzylmercury chloride with bromine in carbon tetrachloride. Russ Chem Bull 12, 1208–1209 (1963). https://doi.org/10.1007/BF00849686

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Keywords

  • Chloride
  • Permeability
  • CCl4
  • Bromine
  • Tetrachloride