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Reactions of hydrazones and azines with metal salts Communication 5. Reactions of hydrazones and azines with mercuric halides

Conclusions

Hydrazones and azines of acetaldehyde, acetone, butanone, cyclohexanone, cyclopentanone, camphor, 2,3-bornanedione, and acetophenone react with mercuric chloride and bromide with formation of complexes between the reactants of general composition (R2C=N-NH2)·nHgX2; (R2C=N-N=CR2)·nHgX2, in which X=C1 or Br and n=1 or 2.

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Literature cited

  1. 1.

    A. S. Gudkova, O. A. Reutov, and M. Ya. Aleinikova, Izv. AN SSSR, Otd. khim. n.,1962, 1382.

  2. 2.

    Yu. A. Zhdanov and O. E. Shelepin, Izv. vuzov. khimiya,2, 200 (1959).

  3. 3.

    A. N. Nesmeyanov, O. A. Reutov, A. S. Loseva, and M. Ya. Khorlina, Izv. AN SSSR, Otd. khim. n.,1958, 1315.

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Additional information

For Communication 4 see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 844–848, May, 1966.

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Gudkova, A.S., Aleinikova, M.Y. & Reutov, O.A. Reactions of hydrazones and azines with metal salts Communication 5. Reactions of hydrazones and azines with mercuric halides. Russ Chem Bull 15, 807–811 (1966). https://doi.org/10.1007/BF00849376

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Keywords

  • Acetaldehyde
  • Chloride
  • Acetone
  • Bromide
  • Halide