Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

The formation of magnesium perperoxide Mg(O2)2 in the reaction of magnesium peroxide with ozone

  • 78 Accesses

  • 2 Citations

Conclusions

  1. 1.

    The possibility of the formation of a new perperoxide magnesium perperoxide Mg (O2)2 at −85 to −65° in the reaction of ozone, dissolved in Freon-12, with magnesium peroxide, suspended in the same medium, was demonstrated.

  2. 2.

    Preparations were isolated containing ∼60% Mg(O2)2. The individuality of magnesium perperoxide was confirmed by the EPR method. The limit of its thermal stability −35 to −29° was established by the method of differential thermal analysis.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    I. I. Vol'nov, S. A. Tokareva, E. I. Latysheva, and V. I. Klimanov, Izv. Akad. Nauk SSSR, Ser. Khim., 2365 (1967).

  2. 2.

    I. I. Vol'nov, S. A. Tokareva, V. I. Klimanov, and G. P. Pilinenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1267 (1966).

  3. 3.

    S. A. Tokareva and G. P. Pilipenko, Zh. Analiticheskoi Khim.,21, 380 (1966).

  4. 4.

    I. E. Bennet, D. I. E. Ingram, and M. C. R. Symons, Philos. Mag.,46, 443 (1955).

  5. 5.

    I. E. Bennet and D. I. E. Ingram, Proc. Phys. Soc.,69A, 556 (1955).

  6. 6.

    T. Henriksen, Radiation Res.,23, 63 (1964).

  7. 7.

    A. D. McLachlam, M. C. R. Symons, and H. G. Towsend, J. Chem. Soc., 952, (1959).

  8. 8.

    G. G. Tsurinov, The Pyrometer of N. S. Kurnakov [in Russian], Izd-vo AN SSSR (1958), p. 63.

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 513–516, March, 1970.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Vol'nov, I.I., Tokareva, S.A., Belevskii, V.N. et al. The formation of magnesium perperoxide Mg(O2)2 in the reaction of magnesium peroxide with ozone. Russ Chem Bull 19, 468–471 (1970). https://doi.org/10.1007/BF00848959

Download citation

Keywords

  • Peroxide
  • Magnesium
  • Ozone
  • Thermal Stability
  • Thermal Analysis