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Change in the selectivity of the action of catalysts during the hydrogenation of the dienone group Communication 3. Modification of cobalt catalysts by cadmium

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Conclusions

  1. 1.

    On Co — ZnO and Co — Al2O3 catalysts, 6-methylheptadiene-3,5-one-2 adds hydrogen both at the 3,4-double bond and at the 5,6-bond.

  2. 2.

    The addition of cadmium exerts a modifying effect upon cobalt catalysts: the dienone is hydrogenated primarily at the 3,4-double bond, conjugated with the C=O group.

  3. 3.

    In the presence of a Co — Cd catalyst, applied on activated charcoal, at 120° the dienone is hydrogenated to a substantial degree at the carbonyl group.

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Literature cited

  1. 1.

    L. Kh. Freidlin, N. V. Borunova, G. I. Samokhvalov, M. A. Miropol'skaya, M. Ts. Yanotovskii, L. I. Gvinter, and N. I. Fedotova, Izv. AN SSSR, Ser. khim.,1964, 996.

  2. 2.

    L. Kh. Freidlin, N. V. Borunova, I. E. Neimark, and L. I. Gvinter, Izv. AN SSSR, Ser. khim.,1966, 1328.

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    N. V. Borunova, L. Kh. Freidlin, and L. I. Gvinter, Izv. AN SSSR, Ser. khim.,1964, 1115.

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    G. M. Badger, G. D. F. Jackson, and W. H. F. Sasse, J. Chem. Soc.,1960, 4438.

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    M. Hansen and K. Anderko, Structures of Binary Alloys [Russian translation], Metallurgizdat, Moscow (1962).

  6. 6.

    L. Kh. Freidlin, N. V. Borunova, L. I. Gvinter, D. I. Lainer, and N. M. Kagan, Neftekhimiya,4, 547 (1964).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1568–1570, September, 1966.

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Borunova, N.V., Freidlin, L.K. & Gvinter, L.I. Change in the selectivity of the action of catalysts during the hydrogenation of the dienone group Communication 3. Modification of cobalt catalysts by cadmium. Russ Chem Bull 15, 1511–1513 (1966). https://doi.org/10.1007/BF00848906

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Keywords

  • Hydrogen
  • Al2O3
  • Cobalt
  • Cadmium
  • Carbonyl