The reaction ofα-ethylvanillyl alcohol,α-ethylveratryl alcohol, and also eugenol with sodium bisulfite solutions were investigated over a wide pH range at 135°.
As well as sulfo derivatives, these model compounds give a certain amount of dimers with an indan structure. The relative yields of unchanged monomer, sulfo derivative, and dimer depend on the nature of the model compound and the reaction conditions.
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This article is published in accordance with a resolution of the conference of Editors in Chief of Journals of the USSR Academy of Sciences of July 12, 1962, as a dissertation paper by V. V. Elkin.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 1788–1785, October, 1966.
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Elkin, V.V., Shorygina, N.N. Reactions of some lignin models with sodium bisulfite. Russ Chem Bull 15, 1726–1731 (1966). https://doi.org/10.1007/BF00848711
- Model Compound