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Chemistry of polyenic and polyynic compounds Communication 18. Diacetylenic amines

Conclusions

  1. 1.

    Some diacetylenic primary amines were synthesized from tertiary diacetylenic chlorides prepared from the corresponding alcohols.

  2. 2.

    Alkylation and Mannich reactions of 1,1-dimethyl-2,4-pentadiynylamine were studied.

  3. 3.

    It was shown that diacetylenic hydrocarbons containing a tertiary alkyl group can be synthesized from 5-chloro-5-methyl-1,3-hexadiyne.

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Literature cited

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    M. J. Marszak, An. Marszak-Fleury, J. Jacob, and G. Montezin, Compt. rend.,231, 80, 186 (1950).

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    G. F. Hennion and L. Price, J. Organ. Chem.,27, 1587 (1962).

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    B. P. Gusev, V. V. Tatarchuk, I. N. Azerbaev, and V. F. Kucherov, Izv. AN SSSR. Ser. khim.,1965, 846.

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    B. P. Gusev and V. F. Kucherov, Izv. AN SSSR. Otd. khim. n.,1962, 1062, 1067.

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    G. F. Hennion, J. J. Schechan, and D. E. Maloney, J. Amer. Chem. Soc.,72, 3542 (1950).

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    W. Chodkiewicz, Ann. chimie,2, 819 (1957).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1209–1213, July, 1966.

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Gusev, B.P., Tatarchuk, V.V., Azerbaev, I.N. et al. Chemistry of polyenic and polyynic compounds Communication 18. Diacetylenic amines. Russ Chem Bull 15, 1163–1166 (1966). https://doi.org/10.1007/BF00847754

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Keywords

  • Alcohol
  • Chloride
  • Hydrocarbon
  • Alkyl Group
  • Primary Amine