Some diacetylenic primary amines were synthesized from tertiary diacetylenic chlorides prepared from the corresponding alcohols.
Alkylation and Mannich reactions of 1,1-dimethyl-2,4-pentadiynylamine were studied.
It was shown that diacetylenic hydrocarbons containing a tertiary alkyl group can be synthesized from 5-chloro-5-methyl-1,3-hexadiyne.
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Gusev, B.P., Tatarchuk, V.V., Azerbaev, I.N. et al. Chemistry of polyenic and polyynic compounds Communication 18. Diacetylenic amines. Russ Chem Bull 15, 1163–1166 (1966). https://doi.org/10.1007/BF00847754
- Alkyl Group
- Primary Amine