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Condensation of hexafluoroacetone with cyanohydrins

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Summary

  1. 1.

    The reaction of hexafluoroacetone imine with the amide of p-methoxymandelic acid gave 2,2-bis(trifluoromethyl)-5-p-methoxyphenyl-4-oxazolidone.

  2. 2.

    A study was made of the condensation of hexafluoroacetone with glycolonitrile and with ethylene cyanohydrin.

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Literature cited

  1. 1.

    Yu. V Zeifman and N. P. Gambaryan, Izv. AN SSSR, Ser. Khim., 1964, No. 9,

  2. 2.

    Yu. V. Zeifman, N. P. Gambaryan, and I. L. Knunyants, Dokl. AN SSSR,153, 1334 (1963).

  3. 3.

    I. L. Knunyants and Yu. A. Cheburkov, Izv. AN SSSR, Otd. Khim. Nauk,1960, 678.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1687–1687, September, 1964

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Zeifman, Y.V., Gambaryan, N.P. Condensation of hexafluoroacetone with cyanohydrins. Russ Chem Bull 13, 1589–1591 (1964). https://doi.org/10.1007/BF00846297

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Keywords

  • Ethylene
  • Amide
  • Trifluoromethyl
  • Hexafluoroacetone
  • Glycolonitrile