Eightα-alkyl-4-hydroxy-3,5-ditert-butylbenzyl halides were produced by addition of the hydrogen halides toα-alkyl-2,6-ditert-butylmethylenequinones.
α-Alkyl-4-hydroxy-3,5-ditert-butylbenzonitriles and 4-(α-N,N-dialkylamino)alkyl-2,6-ditert-butylphenols were produced by the reactions ofα-alkyl-4-hydroxy-3,5-ditert-butylbenzylbromides (chlorides) with sodium cyanide and secondary amines.
A new method of synthesizing 4-sec-alkyl-2, 6-ditert-butylphenols was proposed.
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Volod'kin, A.A., Ershov, V.V., Ostapets-Sveshnikova, G.D. et al. Reaction ofα-alkyl-4-hydroxy-3,5-ditert-butylbenzyl halides with certain nucleophilic agents. Russ Chem Bull 15, 1030–1032 (1966). https://doi.org/10.1007/BF00846061