Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Reaction ofα-alkyl-4-hydroxy-3,5-ditert-butylbenzyl halides with certain nucleophilic agents

  • 22 Accesses

Conclusions

  1. 1.

    Eightα-alkyl-4-hydroxy-3,5-ditert-butylbenzyl halides were produced by addition of the hydrogen halides toα-alkyl-2,6-ditert-butylmethylenequinones.

  2. 2.

    α-Alkyl-4-hydroxy-3,5-ditert-butylbenzonitriles and 4-(α-N,N-dialkylamino)alkyl-2,6-ditert-butylphenols were produced by the reactions ofα-alkyl-4-hydroxy-3,5-ditert-butylbenzylbromides (chlorides) with sodium cyanide and secondary amines.

  3. 3.

    A new method of synthesizing 4-sec-alkyl-2, 6-ditert-butylphenols was proposed.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    A. A. Volod'kin and V. V. Ershov, Izv. AN SSSR, Otd. Khim. N.,1962, 342.

  2. 2.

    A. A. Volod'kin, G. D. Ostapets-Sveshnikova, and V.V. Ershov, Izv. AN SSSR, Ser. Khim.,1965, 2188.

  3. 3.

    A. A. Volod'kin and V. V. Ershov, Izv. AN SSSR, Otd. Khim. N.,1962, 1292.

  4. 4.

    Yu. Bruk and R. Yu. Rachinskii, Zh. Obshch. Khimii,34, 2983 (1964).

  5. 5.

    N. M. Émanuél', N. P. Konovalova, and L. M. Dronova, Dokl. AN SSSR,143, 737 (1962).

  6. 6.

    G. A. Kukushkina, L. B. Gorbacheva, and N. M. Émanuél', Dokl. AN SSSR,146, 1206 (1962).

  7. 7.

    V. V. Ershov, A. A. Volod'kin, and G. D. Ostapets-Sveshnikova, Izv. AN SSSR, Ser. Khim.,1966, 928.

  8. 8.

    J. Hamada and T. Fujisaki, J. Chem. Soc. Japan82, 898 (1961).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1081–1083, June, 1966.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Volod'kin, A.A., Ershov, V.V., Ostapets-Sveshnikova, G.D. et al. Reaction ofα-alkyl-4-hydroxy-3,5-ditert-butylbenzyl halides with certain nucleophilic agents. Russ Chem Bull 15, 1030–1032 (1966). https://doi.org/10.1007/BF00846061

Download citation

Keywords

  • Hydrogen
  • Sodium
  • Chloride
  • Cyanide
  • Halide