An ionic-chain mechanism of the isotopic exchange of the hydrogen of methylcyclohexane in acid media was demonstrated by comparing the rate of isotopic exchange of hydrogen and the rate of absorption of bromine by methylcyclohexane in a solution of trifluoroacetic and sulfuric acids.
Participation of the olefin in the reaction of isotopic exchange of the hydrogen of methylcyclohexane in acid media was demonstrated.
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Kursanov, D.N., Setkina, V.N. & Fok, N.V. Hydrogen exchange of saturated hydrocarbons in homogeneous media Communication 3. Ionic-chain mechanism of the reaction of isotopic exchange of the hydrogen of methylcyclohexane in solutions of trifluoroacetic and sulfuric acids. Russ Chem Bull 15, 931–935 (1966). https://doi.org/10.1007/BF00846042
- Sulfuric Acid
- Acid Medium