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Synthesis and reactions of amide mercaptals

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Summary

  1. 1.

    A new method was developed for the synthesis of formamide mercaptals by the reaction of thiols with the dimethyl sulfate complexes of amides in presence of an alkaline agent.

  2. 2.

    A study was made of some reactions of amide mercaptals with thiols, alcohols, secondary amines, amides, and other compounds containing mobile hydrogen.

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Literature cited

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Additional information

This article is published in accordance with a resolution of the Conference of Editors-in-Chief of Journals of the Academy of Sciences of the USSR of July 12, 1962, as a dissertation paper by I. A. Ivanova.

The authors thank E. M. Popov and G. M. Andrianova for spectroscopic determinations and useful consultation.

Translated from Izvestiya Akademii Nauk SSSR, Khimicheskaya, No. 12, pp. 2179–2187, December, 1965

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Ivanova, I.A., Fedorov, B.P. & Stoyanovich, F.M. Synthesis and reactions of amide mercaptals. Russ Chem Bull 14, 2143–2149 (1965). https://doi.org/10.1007/BF00846003

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Keywords

  • Hydrogen
  • Alcohol
  • Sulfate
  • Amide
  • Dimethyl