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Stereochemistry of cyclic compounds Communication 63. Stereochemistry of the bromination of 4-methyl-cis-4-cyclohexene-1,2-dicarboxylic acid and its anhydride

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Summary

The stereochemistry of the bromination of 4-methyl-cis-4-cyclohexene-l,2-dicarboxylic acid (I) and its anhydride (II) was studied. The spatial structures of the products were proved, and a possible mechanism scheme for their formation was discussed.

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Literature cited

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    V. F. Kucherov, A. L. Shabanov, and A. S. Onishchenko, Izv. AN SSSR, Otd. Khim. n., 1963, 844.

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    A. S. Onishchenko, A. L. Shabanov, and V. F. Kucherov, Izv. AN SSSR, Otd. khim. n., 1963, 852.

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    K. Crewe, A. Heinke, and Ch. Sommer, Chem. Ber.,89, 1978 (1956).

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    A. L. Shabanov, A. S. Onishchenko, and V. F. Kucherov, Izv. AN SSSR, Otd. khim. n., 1963, 1790.

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    I. N. Nazarov, V. F. Kucherov, and V. M. Andreev, Izv. AN SSSR, Otd. khim. n., 1955, 289; 1956, 951; 1959, 1058.

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This article is published in accordance with a resolution of the Conference of Chief Editors of the Journals of the Academy of Sciences of the USSR, July 12, 1962, as a dissertation paper by A. L. Shabanov.

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Shabanov, A.L., Onishchenko, A.S. & Kucherov, V.F. Stereochemistry of cyclic compounds Communication 63. Stereochemistry of the bromination of 4-methyl-cis-4-cyclohexene-1,2-dicarboxylic acid and its anhydride. Russ Chem Bull 12, 1648–1652 (1963). https://doi.org/10.1007/BF00845794

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Keywords

  • Anhydride
  • Spatial Structure
  • Dicarboxylic Acid
  • Cyclic Compound
  • Mechanism Scheme