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Triterpenoid saponins Communication 15. Clematoside C-A triterpenoid oligoside from the roots of the manchurian clematis (Clematis manshurica RUPR.)

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Summary

  1. 1.

    From the roots ofClematis manshurica Rupr. a triterpene saponin-a glycoside of oleanolic acid called clematoside C-was isolated.

  2. 2.

    Clematoside C is a decaoside of oleanolic acid and contains residues of glucose, arabinose, xylose, and rhamnose in the proportions 5∶1∶1∶3.

  3. 3.

    Clematoside C is an O-acyl glycoside in which a carbohydrate chain consisting of glucose and rhamnose residues is attached at the hindered carboxy group. At the 3-position of the genin a carbohydrate chain containing glucose, arabinose, xylose, and rhamnose residues is attached.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 811–818, May, 1965 Original article submitted May 24, 1963

For Communication 13 in this series, “Triterpenoid Saponins,” see [13]; for Communication 14 see [14].

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Khorlin, A.Y., Chirva, V.Y. & Kochetkov, N.K. Triterpenoid saponins Communication 15. Clematoside C-A triterpenoid oligoside from the roots of the manchurian clematis (Clematis manshurica RUPR.). Russ Chem Bull 14, 790–795 (1965). https://doi.org/10.1007/BF00845689

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Keywords

  • Glucose
  • Carbohydrate
  • Xylose
  • Glycoside
  • Saponin