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Saturated vapor pressure of certain stable free radicals

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  1. 1.

    The saturated vapor pressures of certain stable free radicals were studied for the first time by the effusion method, and their heats of sublimation were calculated from these values.

  2. 2.

    The saturated vapor pressure of free radicals is higher at the same temperatures than in the corresponding hydroxylamines.

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Literature cited

  1. 1.

    K. Meyer and H. Gottlieb-Billroth, Ber.,52, 1476 (1919).

  2. 2.

    É. G. Rozantsev and M. B. Neiman, Tetrahedron,20, 131 (1964).

  3. 3.

    É. G. Rozantsev, Izv. AN SSSR, Ser. khim.,1964, 1321.

  4. 4.

    É. G. Rozantsev, Izv. AN SSSR, Ser. khim.,1964, 1362.

  5. 5.

    S. Deshman, Scientific Bases of Vacuum Technology [Russian translation], IL, Moscow (1950).

  6. 6.

    M. Rossman and J. Yarwood, J. Chem. Phys.,21, 1406 (1953).

  7. 7.

    A. M. Chaikin, Zh. fiz. khimii,36, 130 (1962).

  8. 8.

    A. Gillem and E. Stern, Electronic Absorption Spectra of Organic Compounds [Russian translation], IL, Moscow (1957).

  9. 9.

    Yan Stradyn', Polarography of Organic Compounds [in Russian], Izd. AN Latv. SSR, Riga (1961).

  10. 10.

    S. I. Zhdanov and A. N. Frumkin, Dokl. AN SSSR,92, 789 (1953).

  11. 11.

    J. Smith and J. Waller, Trans. Faraday Soc.,46, 290 (1950).

  12. 12.

    N. Levitan, J. Kolthoff, and V. Clark, J. Amer. Chem. Soc.,65, 2265 (1943).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 800–805, May, 1965 Original article submitted July 8, 1964

The article is published on the basis of the resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences, USSR of July 12, 1962 as the dissertation work of L. A. Kalashnikova.

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Kalashnikova, L.A., Rozantsev, É.G. & Chaikin, A.M. Saturated vapor pressure of certain stable free radicals. Russ Chem Bull 14, 782–785 (1965).

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  • Free Radical
  • Vapor Pressure
  • Hydroxylamine
  • Saturated Vapor
  • Saturated Vapor Pressure