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Synthesis of γ-diketones by the method of conjugated hydrogenolysi s

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Summary

1-Furylbutanol-3 and 1-furylpentanol-3 undergo conversions as the result of conjugated hydrogenolysis with hydrogenation in the vapor phase on skeletal Ni-Al at 240°-the former to hexanedione-2,5, heptanedione-2,5, and octanedione-2,5 in a total yield of 30%, the latter to heptanedione-2,5, octanedione-3,6 and nonanedione-3,6, in the same total yield.

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Literature cited

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    I. F. Bel'skii and N. I. Shuikin, Dokl. AN SSSR128, 945 (1959).

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    I. F. Bel'skii and R. A. Karakhanov, Izv. AN SSSR, Otd. Khim. N.1962, 907.

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    I. F. Bel'skii Izv. AN SSSR, Otd. Khim. N.1962, 142.

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    N. I. Shuikin and I. F. Bel'skii, Dokl. AN SSSR,131, 109 (1960).

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    N. I. Shuikin and I. F. Bel'skii, Dokl. AN SSSR115, 330 (1957).

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Shuikin, N.I., Bel'skii, I.F., Karakhanov, R.A. et al. Synthesis of γ-diketones by the method of conjugated hydrogenolysi s. Russ Chem Bull 13, 697–698 (1964). https://doi.org/10.1007/BF00845326

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Keywords

  • Hydrogenation
  • Vapor Phase
  • Total Yield