1-Furylbutanol-3 and 1-furylpentanol-3 undergo conversions as the result of conjugated hydrogenolysis with hydrogenation in the vapor phase on skeletal Ni-Al at 240°-the former to hexanedione-2,5, heptanedione-2,5, and octanedione-2,5 in a total yield of 30%, the latter to heptanedione-2,5, octanedione-3,6 and nonanedione-3,6, in the same total yield.
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I. F. Bel'skii and N. I. Shuikin, Dokl. AN SSSR128, 945 (1959).
I. F. Bel'skii and R. A. Karakhanov, Izv. AN SSSR, Otd. Khim. N.1962, 907.
I. F. Bel'skii Izv. AN SSSR, Otd. Khim. N.1962, 142.
N. I. Shuikin and I. F. Bel'skii, Dokl. AN SSSR,131, 109 (1960).
N. I. Shuikin and I. F. Bel'skii, Dokl. AN SSSR115, 330 (1957).
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Shuikin, N.I., Bel'skii, I.F., Karakhanov, R.A. et al. Synthesis of γ-diketones by the method of conjugated hydrogenolysi s. Russ Chem Bull 13, 697–698 (1964). https://doi.org/10.1007/BF00845326
- Vapor Phase
- Total Yield