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Liquid phase oxidation of the heptane-hexane fraction of rectified gasoline with the recycling of the intermediate oxidation products

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Conclusions

  1. 1.

    The final products from the oxidation of the 35–62° C fraction of rectified gasoline with the recycling of the intermediate products are mainly formic, acetic, and propionic acids.

  2. 2.

    The yield of desired products attains 80–90% based on the consumed gasoline.

  3. 3.

    The oxidation of gasoline with the recycling of the intermediate products makes it possible to simplify the scheme for the separation of the useful products significantly, bringing it to the separation of the aqueous concentrate of the C1-C3 acids.

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Literature cited

  1. 1.

    D. V. Mushenko, G. N. Gvozdovskii, T. F. Ignat'eva, and M. I. Tamik, Khim. i tekhnol. topliv i masel, No. 6 (1965).

  2. 2.

    T. N. Gvozdovskii, Khim. i tekhnol. topliv i masel, No. 9 (1965).

  3. 4.

    A. N. Aleksandrov, Ya. I. Shmulyakovskii, and M. I. Dement'eva, Methods of Studying the Products of Petroleum Treatment and Petrochemical Synthesis [in Russian]. State Fuel Technology Press (1962), pp. 173, 190.

  4. 4.

    E. T. Denisov, Kinetika i kataliz, sbornik statei., Acad. Sci. USSR Press (1962), pp. 95–102.

  5. 5.

    S. Jenkins, J. Amer. Chem.,57 (1935), p. 273.

  6. 6.

    D. B. Sharp, S. E. Whitcomb, and L. W. Patton, Moorhead, J. Amer. Chem. Soc.,74 (1952), p. 1802.

  7. 7.

    W. Pritzkow, Ber., Bd. 87, (1954), p. 1668.

  8. 8.

    W. Pritzkow, Ber., Bd. 88 (1955), p. 572.

  9. 9.

    D. G. Kporre, Z. K. Maizus, L. K. Obukhova, and N. M. Émanuél, Uspekhi khimii,26(4) (1957), p. 416.

  10. 10.

    I. V. Berezin, B. I. Mokalets, and L. G. Chuchukina, ZhOKh,28, No. 10 (1958), p. 2718.

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Mushenko, D.V., Gvozdovskii, G.N. & Semenova, V.V. Liquid phase oxidation of the heptane-hexane fraction of rectified gasoline with the recycling of the intermediate oxidation products. Chem Technol Fuels Oils 1, 836–840 (1965). https://doi.org/10.1007/BF00719186

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Keywords

  • Oxidation
  • Acetic
  • Liquid Phase
  • Gasoline
  • Oxidation Product