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A study of complex mixtures of natural substances by the defocusing and dadi methods. V. Steroid metabolites of the phytopathogenic fungusVerticillium dahliae

Abstract

The mixture of steroid metabolites of the phytopathogenic fungusV. dahliae have been studied by high- and low-resolution mass spectrometry, metastable defocusing, and the direct analysis of daughter ions (DADI). On the basis of the analysis of the spectral results obtained for the mixtures themselves and for the products of their tosylation the presence in the samples studied of mixtures of β-sitosterol, stigmasterol, and cholesterol has been established. Probable structures have been proposed for the components of the mixture with m/z values of the molecular ions of 426, 424, and 412.

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Literature cited

  1. 1.

    A. A. Akhrem and Titov, Steroids and Microorganisms [in Russian], Moscow (1970), p. 10.

  2. 2.

    J. Diekman and C. Djerassi, J. Org. Chem.,32, 1005 (1967).

  3. 3.

    L. Minale and G. Sodano, J. Chem. Soc., Perkin Trans. I, 1888 (1974).

  4. 4.

    A. K. Kasimov, Kh. A. Aslanov, and R. R. Razakov, Uzb. Khim. Zh., No. 5, 28 (1983).

  5. 5.

    D. H. Smith, C. Djerassi, K. H. Maurer, and U. Rapp, J. Am. Chem. Soc.,96, 3482 (1974).

  6. 6.

    R. R. Razakov, Kh. A. Aslanov, A. S. Sadykov, and B. V. Rozynov, Bioorg. Khim.,3, 600 (1977).

  7. 7.

    O. S. Otroshchenko, N. N. Stepanichenko, S. D. Gusakova, and S. Z. Mukhamedzhanov, Khim. Prir. Soedin., 275 (1979).

  8. 8.

    A. A. Bell, R. D. Stipanovic, and J. E. Puhalla, Tetrahedron,32, 1353 (1976).

  9. 9.

    R. D. Stipanovic and A. A. Bell, J. Org. Chem.,41, 2468 (1976).

  10. 10.

    R. R. Razakov, A. K. Kasimov, Kh. A. Aslanov, and A. S. Sadykov, Bioorg. Khim.,6, 944 (1980).

  11. 11.

    F. J. Brown and C. Djerassi, J. Am. Chem. Soc.,102, 807 (1980).

  12. 12.

    R. R. Razakov, A. K. Kasimov, Kh. A. Aslanov, and A. S. Sadykov, Khim. Prir. Soedin., 81 (1981).

  13. 13.

    F. J. Schmitz and T. Pattabhiraman, J. Am. Chem. Soc.,92, 6073 (1970).

  14. 14.

    J. D. Welt and J. L. Laster, Lipids,9, 575 (1974).

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Additional information

Institute of Bioorganic Chemistry, Academy of Sciences of the Uzbek SSR, Tashkent. V. I. Lenin Tashkent State University. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 227–232, March–April, 1985.

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Razakov, R.R., Kasimov, A.K., Aslanov, K.A. et al. A study of complex mixtures of natural substances by the defocusing and dadi methods. V. Steroid metabolites of the phytopathogenic fungusVerticillium dahliae . Chem Nat Compd 21, 212–217 (1985). https://doi.org/10.1007/BF00714915

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Keywords

  • Cholesterol
  • Mass Spectrometry
  • Steroid
  • Organic Chemistry
  • Complex Mixture