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Dinitramide and its salts

7. Spectra and structure of dinitramide salts

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The vibrational and electronic spectra of dinitramide salts MN(NO2)2 (M=K, Na, Li, NH4, Fe, Ag, Mn, Mg, Rb, C(NH2)3) have been studied. The IR and Raman spectra of solutions and melts of the salts have been satisfactorily interpreted on the basis of the anion model withC 2v symmetry. The complication of the spectra in the crystalline phase has been explained by restructurization of the anion that reduces its symmetry and makes the nitro groups nonequivalent.

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    O. A. Luk'yanov, O. V. Anikin, V. P. Gorelik, and V. A. Tartakovsky,Izv. Akad. Nauk, Ser. Khim., 1994, 1610 [Russ. Chem. Bull., 1994,43, 1457 (Engl. Transl.)].

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    V. A. Shlyapochnikov,Kolebatel'nye spektry alifaticheskikh nitrosoedinenii [Vibrational Spectra of Aliphatic Nitro Compounds], Nauka, Moscow, 1989 (in Russian).

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    V. A. Shlyapochnikov, N. O. Cherskaya, O. A. Luk'yanov, V. P. Gorelik, and V. A. Tartakovsky,Izv. Akad. Nauk, Ser. Khim., 1994, 1546 [Russ. Chem. Bull., 1994,43, 1457 (Engl. Transl.)].

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    N. O. Cherskaya, V. A. Shlyapochnikov, V. P. Ivshin, and T. N. Ivshina,Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 1533 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986,35, 1388 (Engl. Transl.)].

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For part 6, seeIzv. Akad. Nauk, Ser. Khim., 1995, 113 [Russ. Chem. Bull.,44, 108 (Engl. Transl.)].

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1508–1512, August, 1995.

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Shlyapochnikov, V.A., Oleneva, G.I., Cherskaya, N.O. et al. Dinitramide and its salts. Russ Chem Bull 44, 1449–1453 (1995). https://doi.org/10.1007/BF00714427

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Key words

  • dinitramide salts, structure
  • IR spectra
  • Raman spectra
  • UV spectra