The vibrational and electronic spectra of dinitramide salts MN(NO2)2 (M=K, Na, Li, NH4, Fe, Ag, Mn, Mg, Rb, C(NH2)3) have been studied. The IR and Raman spectra of solutions and melts of the salts have been satisfactorily interpreted on the basis of the anion model withC 2v symmetry. The complication of the spectra in the crystalline phase has been explained by restructurization of the anion that reduces its symmetry and makes the nitro groups nonequivalent.
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O. A. Luk'yanov, O. V. Anikin, V. P. Gorelik, and V. A. Tartakovsky,Izv. Akad. Nauk, Ser. Khim., 1994, 1610 [Russ. Chem. Bull., 1994,43, 1457 (Engl. Transl.)].
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1508–1512, August, 1995.
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Shlyapochnikov, V.A., Oleneva, G.I., Cherskaya, N.O. et al. Dinitramide and its salts. Russ Chem Bull 44, 1449–1453 (1995). https://doi.org/10.1007/BF00714427
- dinitramide salts, structure
- IR spectra
- Raman spectra
- UV spectra