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Photoluminescence of aqueous solutions of uranyl nitrate containing sodium tetrametaphosphate

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Abstract

Solutions (10−5 to 5×10−2 M) of UO2(NO3)2 have been used in the presence of 2 wt.% Na4P4O12, with excitation by a mercury arc over the range 3200–3800 Å. The emission and absorption spectra of the complex are reported; the first is narrow and has peaks at 4910, 5150, and 5400 Å. This spectrum is the same whether the tetrametaphosphate anion has the chair configuration or the boat one.

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Dombrovskii, N.M., Guminetskii, S.G., Sorochenko, L.T. et al. Photoluminescence of aqueous solutions of uranyl nitrate containing sodium tetrametaphosphate. J Appl Spectrosc 6, 433–434 (1967). https://doi.org/10.1007/BF00707520

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Keywords

  • Sodium
  • Nitrate
  • Aqueous Solution
  • Analytical Chemistry
  • Mercury