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Variation of luminescence properties of the reaction solution during preparation of a component of Ziegler-Natta catalyst by the reaction of Tb with Ph3CCl

Abstract

Photoluminescence is used to test lanthanide-C bonds and to identify unstable intermediates in the synthesis of Ph3CTbCl2, a component of Ziegler-Natta catalyst.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2053–2055, October, 1995.

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Bulgakov, R.G., Bikbaeva, G.G., Akhmadeev, R.G. et al. Variation of luminescence properties of the reaction solution during preparation of a component of Ziegler-Natta catalyst by the reaction of Tb with Ph3CCl. Russ Chem Bull 44, 1972–1973 (1995). https://doi.org/10.1007/BF00707243

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Key words

  • lanthanides
  • photoluminescence
  • catalyst