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Reaction of 5-aryl-2-tosylmethylimino-2,3-dihydro-3-furanones with substitutedN-(benzylidene)benzylamines. Crystal structure of 1-benzyl-5-p-methoxyphenyl-2-(p-chlorobenzoyl)acetylimidazole

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Abstract

5-Aryl-2-aroylacetyl-1-benzylimidazoles were synthesized by treatment of 5-aryl-2-tosylmethylimino-2, 3-dihydro-3-furanones withN-(benzylidene)benzylamines containing electron-donating substitutents in the benzylidene moiety. The structure of 1-benzyl-5-p)-methoxyphenyl-2-(p-chlorobenzoyl)acetylimidazole was studied by X-ray diffraction.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2013–2016, October, 1995.

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Shurov, S.N., Yanborisov, T.N., Andreichikov, Y.S. et al. Reaction of 5-aryl-2-tosylmethylimino-2,3-dihydro-3-furanones with substitutedN-(benzylidene)benzylamines. Crystal structure of 1-benzyl-5-p-methoxyphenyl-2-(p-chlorobenzoyl)acetylimidazole. Russ Chem Bull 44, 1933–1936 (1995). https://doi.org/10.1007/BF00707230

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Key words

  • N-substituted 2-imino-5-aryl-2,3-dihydro-3-furanones, recyclization
  • 5-aryl-2-aroylacetyl-1-benzylimidazoles
  • X-ray analysis