Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Destruction ofB-polyfluorosubstitutedo-carboranes into anions ofB-fluorosubstitutednido-7,8-dicarbaundecaborates by the action of ethanolic alkali and amines

  • 26 Accesses

  • 10 Citations

Abstract

The destruction ofB-polyfluorosubstitutedo-carboranes by the action of ethanolic alkali and amines was studied. The destraction of trifluoro-o-carborane was found to occur regioselectively. The nature of the amine was shown to affect the stereochemistry of the destruction of trifluoro-o-carborane. The intermediate of the reaction of tetrafiuoro-o-carborane with diethylamine was detected.

This is a preview of subscription content, log in to check access.

References

  1. 1.

    R. A. Wiesbock and M. F. Hawthorne,J. Am. Chem. Soc., 1964,86, 164.

  2. 2.

    L. I. Zakharkin and V. N. Kalinin,Izv. Akad. Nauk SSSR, Ser. Khim., 1965, 579 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1965, 568 (Engl. Transl.)].

  3. 3.

    L. I. Zakharkin and V. S. Kirillova,Izv. Akad. Nauk SSSR, Ser. Khim., 1975, 2596 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1975,24, No. 11 (Engl. Transl.)].

  4. 4.

    V. N. Lebedev, L. I. Zakharkin, G. N. Kartsev, and S. M. Ignat'eva,Metalloorg. Khim., 1989,2, 1398 [Organomet. Chem. USSR, 1989,2 (Engl. Transl.)].

  5. 5.

    V. N. Lebedev, E. V. Balagurova, A. I. Yanovski, Yu. T. Struchkov, and L. I. Zakharkin,J. Organomet. Chem., 1990,385, 307.

  6. 6.

    I. Buchanan, I. M. Hamilton, D. Reed, and A. I. Weich,J. Chem. Soc., Dalton Trans., 1990, 677.

  7. 7.

    L. I. Zakharkin, G. G. Zhigareva, and V. A. Antonovich,Zh. Obshch. Khim., 1980, 1026 [J. Gen. Chem. USSR, 1980 (Engl. Transl.)].

  8. 8.

    V. N. Lebedev, M. V. Galakhov, V. I. Bakhmutov, and L. I. Zakharkin,Metalloorg. Khim., 1989,2, 940 [Organomet. Chem. USSR, 1989,2 (Engl. Transl.)].

  9. 9.

    M. F. Hawthorne and P. A. Wegner,J. Am. Chem. Soc., 1968,90, 896.

  10. 10.

    L. I. Zakharkin, V. N. Kalinin, and E. G. Rys,Zh. Obshch. Khim., 1977,4, 841 [J. Gen. Chem. USSR, 1977,4 (Engl. Transl.)].

Download references

Author information

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1141–1145, June, 1995.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Lebedev, V.N., Balagurova, E.V. & Zakharkin, L.I. Destruction ofB-polyfluorosubstitutedo-carboranes into anions ofB-fluorosubstitutednido-7,8-dicarbaundecaborates by the action of ethanolic alkali and amines. Russ Chem Bull 44, 1102–1106 (1995). https://doi.org/10.1007/BF00707062

Download citation

Key words

  • B-polyfluorosubstituted
  • o-carboranes
  • B-fluorosubstituted
  • nido-7,8-dicarbaundecaborates