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Reaction of niobium pentachloride with bis(triethylgermyl)cadmium

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Abstract

The reaction of niobium pentachloride with Cd(GeEt3)2 (1 ∶ 1) in THFin vacuo has been studied. The reaction affords Et3GeNbCl4 · THF, which was characterized by elemental analysis and IR spectroscopy. To refine the composition of the compound, the thermolysis of Et3GeNbCl4 · THF at 85 and 180 °C was studied.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1812–1813, October, 1994.

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Lomakova, I.V., Domrachev, G.A., Patrikeeva, N.B. et al. Reaction of niobium pentachloride with bis(triethylgermyl)cadmium. Russ Chem Bull 43, 1717–1718 (1994). https://doi.org/10.1007/BF00703496

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Key words

  • niobium pentachloride
  • reaction with bis(triethylgermyl)cadmium
  • triethylgermylniobium pentachloride
  • monosolvate with THF
  • thermolysis
  • volatile
  • solid products