Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Study of intermolecular interactions and complex formation of aminofurazans by IR spectroscopy

  • 25 Accesses

  • 3 Citations

Abstract

The IR spectra of 3-amino-4-nitrofurazan (1) and 4-amino-4′-nitroazoxyfurazan (2) in the crystalline state and in solutions in CH{in2}Cl{in2}, CCl{in4}, and MeCN have been studied. It was shown that both compounds exist in the solid state as self-associates, which are destroyed on dissolution in an organic solvent. Compouns1 and2 form associate complexes with MeCN, the energies of formation of which are −5 and −3 kcal mol{su−1}, respectively.

This is a preview of subscription content, log in to check access.

References

  1. 1.

    V. M. Bilobrov,Vodorodnaya svyaz' [The Hydrogen Bond], Naukova Dumka, Kiev, 1991, 320 pp. (in Russian).

  2. 2.

    A. Smith,Applied Infrared Spectroscopy, Wiley-Interscience, New York, Chichester, Brisbane, Toronto, 1979.

  3. 3.

    V. A. Shlyapochnikov,Kolebatel'nye spektry alifaticheskikh nitrosoedinenii [Vibrational Spectra of Aliphatic Nitro Compounds], Nauka, Moscow, 1989, 134 pp. (in Russian).

  4. 4.

    L. I. Khmel'nitskii, S. S. Novikov, and T. I. Godovikova,Khimiya furoksanov [Chemistry of Furoxans], Nauka, Moscow, 1981, 328 pp. (in Russian).

  5. 5.

    K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, J. Wiley and Sons, Inc., New York, 1986.

  6. 6.

    V. A. Terent'ev and N. Kh. Shtivel',Zh. Fiz. Khim., 1969,43, 2929 [Russ. J. Phys. Chem., 1969,43 (Engl. Transl.)].

  7. 7.

    N. O. Cherskaya, V. N. Shilenko, and V. A. Shlyapochnikov,Izv. Akad. Nauk SSSR, Ser. Khim., 1972, 620 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1972,21, 581 (Engl. Transl.)].

Download references

Author information

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2242–2246, December, 1994.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Cherskaya, N.O., Kharitonova, O.V., Shlyapochnikov, V.A. et al. Study of intermolecular interactions and complex formation of aminofurazans by IR spectroscopy. Russ Chem Bull 43, 2122–2125 (1994). https://doi.org/10.1007/BF00700185

Download citation

Key words

  • aminofurazans
  • IR spectra
  • associate complexes
  • energy of formation