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Solid-state mechanochemical synthesis of tris(4-imino-2-pentanonato)chromium, Cr[CH3C(NH)CHC(O)CH3]3

Abstract

Tris(4-imino-2-pentanonato)chromium was prepared by solid-state synthesis under conditions of mechanical activation of a mixture of chromium(III) chloride and sodium 4-imino-2-pentanonate and characterized by IR spectroscopy, X-ray diffraction, and electronic absorption spectroscopy.

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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2227–2229, December, 1994.

The present work was carried out as a part of Project No. 1.164 “Mechanochemical Synthesis of Complex Compounds” of The State Scientific and Technical Program “Ecologically Safe Processes in Chemistry and Chemical Technology” with the financial support of the Ministry of Science of the RF.

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Borisov, A.P., Petrova, L.A., Karpova, T.P. et al. Solid-state mechanochemical synthesis of tris(4-imino-2-pentanonato)chromium, Cr[CH3C(NH)CHC(O)CH3]3 . Russ Chem Bull 43, 2107–2109 (1994). https://doi.org/10.1007/BF00700180

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Key words

  • chromium complexes
  • acetylacetoneimine
  • mechanochemical synthesis