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Study of the mechanism of the addition of benzyl bromide to trimethylvinylsilane in the presence of the Fe(CO)5—DMF system

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Abstract

The general kinetics of the addition of benzyl bromide to trimethylvinylsilane in the presence of the Fe(CO)5—DMF system has been studied. The reaction orders with respect to each reagent found in the study correspond to a radical chain mechanism of the process. The metal-complex system takes part only in the initiation stage and only at a strictly defined ratio of the components.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1418–1422, August, 1993.

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Terent'ev, A.B., Gapusenko, S.I. & Vasil'eva, T.T. Study of the mechanism of the addition of benzyl bromide to trimethylvinylsilane in the presence of the Fe(CO)5—DMF system. Russ Chem Bull 42, 1352–1356 (1993). https://doi.org/10.1007/BF00699930

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Key words

  • benzyl bromide, trimethylvinylsilane, addition
  • radicals
  • metal-complex initiation
  • kinetics
  • mechanism