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Synthesis and1H NMR study of some organotin derivatives of diethanolamines


A number of organotin derivatives of diethanolamines (stannocanes) R2Sn(OCH2CH2)2NR', O(SiMe2CH2)2Sn(OCH2CH2)2NR', and Sn[(OCH2CH2)2NR']2 (R = Ph,cyclo-Hex; R' = H, Me, Ph) were synthesized and studied by1H NMR spectroscopy. The effect of steric factors on the ability of molecules of stannocanes to form associates in solutions is discussed.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp.714–718, April, 1994.

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Shiryaev, V.I., Stepina, E.M., Tandura, S.N. et al. Synthesis and1H NMR study of some organotin derivatives of diethanolamines. Russ Chem Bull 43, 666–670 (1994). https://doi.org/10.1007/BF00699845

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Key words

  • organotin compounds
  • stannocanes
  • synthesis
  • NMR
  • steric factors
  • associates