Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Synthesis and1H NMR study of some organotin derivatives of diethanolamines

Abstract

A number of organotin derivatives of diethanolamines (stannocanes) R2Sn(OCH2CH2)2NR', O(SiMe2CH2)2Sn(OCH2CH2)2NR', and Sn[(OCH2CH2)2NR']2 (R = Ph,cyclo-Hex; R' = H, Me, Ph) were synthesized and studied by1H NMR spectroscopy. The effect of steric factors on the ability of molecules of stannocanes to form associates in solutions is discussed.

This is a preview of subscription content, log in to check access.

References

  1. 1.

    V. M. Potapov,Stereokhimiya [Stereochemistry], Khimiya, Moscow, 1988, 237 (in Russian).

  2. 2.

    R. G. Swishera and R. R. Holmes,Organometallics, 1984,3, 365.

  3. 3.

    A. Zschunke, C. Mugge, M. Scheer, K. Jurkschat, and A. Tzschach,J. Crystallographic and Spectroscopic Research, 1983,13, 201.

  4. 4.

    A. Tzschach and K. Jurkschat,Comm. Inorg. Chem., 1983,3, 35.

  5. 5.

    M. Drager and L. Rob,Chem.Ber., 1975,108, 1712.

  6. 6.

    M. Drager and H.-J. Guttmann,J. Organometal. Chem., 1981,212, 171.

  7. 7.

    K. Jurkschat, C. Mugge, A. Tzschach, A. Zschunke, M. F. Larin, V. A. Pestunovich, and M. G. Voronkov,J. Organometal. Chem., 1977,139, 279.

  8. 8.

    A. Zschunke, A. Tzschach, and K. Jurkschat,J Organometal. Chem., 1976,112, 273.

  9. 9.

    S. N. Gurkova, S. N. Tandura, A. I. Gusev, N. V. Alekseev, A. E. Chernyshev, E. M. Stepina, E. A. Kovaleva, A. A. Grachev, and V. I. Shiryaev,Metalloorg. Khim., 1988,1, 839 [Organomet. Chem. USSR, 1988,1 (Engl. Transl.)].

  10. 10.

    V. F. Mironov, E. M. Stepina, and V. I. Shiryaev,Zh. Obshch. Khim., 1972,42, 631 [J. Gen. Chem. USSR, 1972,42 (Engl. Transl.)].

  11. 11.

    A. I. Gusev, V. I. Shiryaev, S. N. Tandura, S. N. Gurkova, E. M. Stepina, V. A. Sharapov, and E. A. Kovaleva,II Vsesoyuz. simp. «Stroenie i reaktsionnaya sposobnost' kremniiorganicheskikh soedinenii», Tez. dokl., [The II-nd All-Union Symp. «Structure and Reactivity of Organosilicon Compounds.» Abstracts.], Irkutsk, 1981, 16 (in Russian).

  12. 12.

    R. C. Mehrotra and V. D. Gupta,Indian J. Chem., 1967,5, 643.

  13. 13.

    R. Fiedler and H. Follner,Monatsh. Chem., 1977,10, 319.

  14. 14.

    C. A. Kraus and R. H. Bullard,J. Am. Chem. Soc., 1929,51, 3605.

  15. 15.

    A. Tzschach and K. Ponicke,Z. Anorg. Allg. Chem., 1975,413, 136.

  16. 16.

    V. A. Pal'm,Osnovy kolichestvennoi teorii organicheskikh reaktsii [Fundamentals of the Quantitative Theory of Organic Reactions], Khimiya, Leningrad, 1977, 319 (Russ. Transl.).

  17. 17.

    A. Kemme, J. Bleidelis, I. Urtane, G. Zelchan, and E. Lukevics,J. Organomet. Chem., 1980,202, 115.

  18. 18.

    Ch. S. Babashinskaya and K. A. Kocheshkov,Zh. Obshch. Khim., 1938,8, 1850 [J. Gen. Chem. USSR, 1938,8 (Engl. Transl.)].

  19. 19.

    K. A. Kocheshkov, N. N. Zemlyanskii, N. I. Sheverdina, and E. M. Panov,Metody elementoorganicheskoi khimii. Germanii, olovo, svinets. [Methods of Organometallic Chemistry. Germanium, Tin, Lead.], Nauka, Moscow, 1968, 215 (in Russian).

Download references

Author information

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp.714–718, April, 1994.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Shiryaev, V.I., Stepina, E.M., Tandura, S.N. et al. Synthesis and1H NMR study of some organotin derivatives of diethanolamines. Russ Chem Bull 43, 666–670 (1994). https://doi.org/10.1007/BF00699845

Download citation

Key words

  • organotin compounds
  • stannocanes
  • synthesis
  • NMR
  • steric factors
  • associates