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Reactions ofN,N-dibromo-tert-butylamine with ketoximes

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Reactions of acetone, cyclohexanone, and adamantanone oximes withN,N-dibromo-tert-butylamine result in the correspondingC-bromo-diazene-N-oxides. In the case of benzophenone oxime,O, O'-(diphenylmethylene)-bis-benzophenone oxime has been obtained.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 176–177, January, 1994.

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Petrova, I.M., Chertanova, L.F. & Chlenov, I.E. Reactions ofN,N-dibromo-tert-butylamine with ketoximes. Russ Chem Bull 43, 173–174 (1994). https://doi.org/10.1007/BF00699164

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Key words

  • oximes
  • diazene-N-oxides
  • N,N-dibromo-tert-butylamine