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Synthesis of η6-tricarbonylchromium derivatives of diphenylmethanofullerene using an organometallic derivative of diazomethane

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Abstract

Isomeric chromotricarbonyl derivatives of diphenylmethanofullerene and -fulleroid have been obtained by the reaction of C60 with benchrotrenyl(phenyl)diazomethane.

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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 780–783, April, 1995.

Authors are thankful to D. V. Zagorevskii for recording the FAB-MS spectrum.

The present work was carried out with financial support from the Russian Foundation for Basic Research (Project No. 93-03-18725) and the Intellectual Cooperation Foundation.

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Nefedova, M.N., Sokolov, V.I. Synthesis of η6-tricarbonylchromium derivatives of diphenylmethanofullerene using an organometallic derivative of diazomethane. Russ Chem Bull 44, 761–764 (1995). https://doi.org/10.1007/BF00698519

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Key words

  • fullerenes
  • methanofullerene
  • fulleroids
  • arenechromiumtricarbonyls