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Alkoxylation ofC-chlorovinylsilanes

Abstract

The alkoxylation and isopropylideneiminoxylation ofC-chlorovinylmethylchlorosilanes with various alcohols and acetone oxime were investigated. A series of newC-chlorovinylmethylalkoxy- and -isopropylideneiminoxysilanes was characterized by IR and1H NMR spectra. The effect of the number of chlorine atoms inC-chlorovinylmethylchlorosilanes on their reactivity in these reactions was determined.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 737–742, April, 1995.

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Lakhtin, V.G., Ryabkov, V.L., Polyakova, M.V. et al. Alkoxylation ofC-chlorovinylsilanes. Russ Chem Bull 44, 718–723 (1995). https://doi.org/10.1007/BF00698510

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Key words

  • C-chlorovinylmethylchlorosilanes, etherification
  • C-chlorovinylmethylalkoxysilanes, alcohols, IR spectra
  • 1H NMR spectra