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Russian Chemical Bulletin

, Volume 42, Issue 3, pp 538–542 | Cite as

Reactivity of ruthenium carbonyl derivatives of lutecium. Molecular structure of (THF)[1, 3-(Me3Si)2C5H3]2Lu(μ-OH)2

  • I. P. Beletskaya
  • A. Z. Voskoboinikov
  • N. I. Kirillov
  • A. I. Gusev
  • A. K. Shestakov
  • I. N. Parshina
Organometallic Chemistry
  • 19 Downloads

Abstract

The reactivity of the ruthenium carbonyl derivatives of lutecium (THF)Cp'2LuRu(CO)2Cp [Cp'=Cp (1) and 1, 3-(Me3Si)2C5H3 (2)] has been studied. It has been shown that the reactions of complex 1 withi.-Pr2CO and of2 with HCl, H2O, and HgCl2 are accompanied by cleavage of the Lu-Ru bond. The reaction of2 with H2O gives [1, 3-(Me3Si)2C5H3]2Lu (μ-OH)2 (3), which has been characterized by X-ray diffraction analysis (MoKα radiation,R=0.0280, 2750 reflections). The crystals are monoclinic,a = 15.638(6) Å,b=15.787(2) Å,c = 12.188(1) Å, β=99.06°,Z= 2, space group P21/n. Centrosymmetric dimer3 has two μ-OH ligands, and the Lu-O and Lu...Lu interatomic distances are 2.264(4) Å (mean) and 3.579(1) Å, respectively. The structure behavior of3 in a THF solution has been discussed.

Key words

ruthenium lutecium molecular structure 

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Copyright information

© Plenum Publishing Corporation 1994

Authors and Affiliations

  • I. P. Beletskaya
    • 1
  • A. Z. Voskoboinikov
    • 2
  • N. I. Kirillov
    • 2
  • A. I. Gusev
    • 2
  • A. K. Shestakov
    • 2
  • I. N. Parshina
    • 2
  1. 1.M. V. Lomonosov Moscow State UniversityMoscowRussian Federation
  2. 2.State Research Institute of the Chemistry and Technology of Organoelement CompoundsMoscowRussian Federation

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