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Adsorption of methanol on sodium faujasites and mordenites

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Calorimetry and IR spectroscopy were used to study the adsorption of methanol on faujasites and mordenites with different Si/Al ratios. It was shown that the disturbance of the OH bonds in CH3OH weakens and the heat of adsorption decreases as the cation content in the zeolites decreases. The protic acid sites in decationized mordenite form strong hydrogen bonds with the adsorbed molecules.

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  1. 1.

    N. N. Avgul, A. G. Bezus, and O. M. Dzhigit,Adv. Chem. Ser., 1971, 184.

  2. 2.

    A. A. Isirikyan and N. I. Regent,XI Vsesoyuzn. Konf. po Kalorimetrii i Khim. Termodinamike [XI All-Union Conf. on Calorimetry and Chemical Thermodynamics], Abstr., Part 2, Novosibirsk, 1986, 51 (in Russian).

  3. 3.

    G. V. Tsitsishvili, E. V. Kobaladze, and A. A. Isirikyan,Izv. Akad. Nauk GSSR. Ser. Khim., 1984,10, 35 (in Russian).

  4. 4.

    K. S. Akhmedov, G. U. Rakhmatkariev, M. M. Dubinin, and A. A. Isirikyan,Izv. Akad. Nauk SSSR, Ser. Khim., 1987, 1717 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987,36, 1587 (Engl. Transl.)].

  5. 5.

    M. M. Dubinin, G. U. Rakhmatkariev, and A. A. Isirikyan,Izv. Akad. Nauk SSSR, Ser. Khim., 1989, 2633 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989,38, 2419 (Engl. Transl.)].

  6. 6.

    H. Thamm,J. Chem. Soc. Faraday Trans., 1, 1989,85, 1.

  7. 7.

    K. K. Pitale, R. A. Rajadhyaksha, A. S. Pendharkar, and A.S. C. Eapen,Curr. Sci., 1988,57, 355.

  8. 8.

    B. Coughan, W. M. Carroll, P. Kavanagh, and J. Nunan,J. Chem. Technol. Biotechnol., 1981,31, 1.

  9. 9.

    W. D. Einicke, U. Messow, R. Scholler, and G. Zahn,J. Chem. Soc., Faraday Trans., 1, 1988,84, 3597.

  10. 10.

    H. K. Beyer and I. Belenykaja,Stud. Surf. Sci. Catal, 1980,5, 203.

  11. 11.

    Compilation of Extra Framework Sites in Zeolites, Ed. W. J.Mortier, Leuven, 1982.

  12. 12.

    K. T. No, H. Chon, T. Ree, and M. S. Jhon,J. Phys. Chem., 1981,85, 2065.

  13. 13.

    S. G. Izmailova, S. S. Khvoshchev, and M. A. Shubaeva,Izv. Akad. Nauk, Ser. Khim., 1992, 2494 [Bull. Acad. Sci., Div. Chem. Sci., 1992,41 (Engl. Transl.)].

  14. 14.

    P. Salvador and W. Kladnig,J. Chem. Soc., Faraday Trans., 1, 1977,73, 1153.

  15. 15.

    S. S. Khvoshchev and A. V. Zverev,J. Colloid Interface Sci., 1991,144, 571.

  16. 16.

    A. V. Zverev and S. S. Khvoshchev,J. Therm. Anal., 1986,31, 773.

  17. 17.

    Ya. I. Ryskin and G. P. Stavitskaya,Zh. Fiz. Khim., 1991,65, 448 [J. Phis. Chem., 1991,65 (Engl. Transl.)].

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 476–479, March, 1993.

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Izmailova, S.G., Karetina, I.V. & Khvoshchev, S.S. Adsorption of methanol on sodium faujasites and mordenites. Russ Chem Bull 42, 427–431 (1993). https://doi.org/10.1007/BF00698422

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Key words

  • zeolites
  • adsorption
  • methanol
  • IR spectra