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Synthesis of 2-(1-alkoxyvinyl)pyridines

Abstract

2-(1-Bromovinyl)pyridine, 2-ethynylpyridine, 2-(1-alkoxyvinyl)pyridines, and 2-(2-alkoxyvinyl)pyridines (the cis and trans isomers) were detected in the reaction mixture by mass spectrometry in the reaction of 2-vinylpyridine with bromine with subsequent dehydrobromination of the addition product with an alcohol solution of alkali. The conditions for the preparation of chromatographically pure compounds were found.

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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 647–650, May, 1978.

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Terent'ev, P.B., Kotova, N.G. Synthesis of 2-(1-alkoxyvinyl)pyridines. Chem Heterocycl Compd 14, 530–533 (1978). https://doi.org/10.1007/BF00673337

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Keywords

  • Alcohol
  • Mass Spectrometry
  • Organic Chemistry
  • Pyridine
  • Bromine