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Hetarylation of cyclopentadiene, indene, and azulene

Abstract

The direct hetarylation of cyclopentadiene, indene, and azulene with several benzopyridines in the presence of acyl halides was studied. It is shown that the most electrophilic N-benzoyl-isoquinolinium salt is capable of hetarylating CH acids with pKa<21.

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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1368–1375, October, 1975.

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Sheinkman, A.K., Samoilenko, G.V., Baranov, S.N. et al. Hetarylation of cyclopentadiene, indene, and azulene. Chem Heterocycl Compd 11, 1168–1173 (1975). https://doi.org/10.1007/BF00667616

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Keywords

  • Indene
  • Organic Chemistry
  • Halide
  • Azulene
  • Cyclopentadiene