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The effect of water vapour on the cyclodextrin-solute interaction in gas-solid chromatography

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Abstract

The effect of water vapour on the interaction between the solutes and a cyclodextrin was studied chromatographically in a gas/solid system. It has been shown that all the sorbates capable of forming inclusion complexes with α-CD are affected by the presence of water, in contrast to the sorbates that do not interact with α-CD, which are unaffected. The measurements were carried out with the cyclodextrin deposited on a solid carrier (Chromosorb W) and with water vapour contained in the mobile phase. Some advantages of this system have been demonstrated for an analytical application.

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Correspondence to E. Smolková-Keulemansová.

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Anděra, L., Smolková-Keulemansová, E. The effect of water vapour on the cyclodextrin-solute interaction in gas-solid chromatography. Journal of Inclusion Phenomena 5, 397–405 (1987). https://doi.org/10.1007/BF00664094

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Key Words

  • Sorbate-cyclodextrin interaction
  • Effect of water vapour
  • Gas-solid chromatography
  • Analytical applications