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Formation and destruction of the O2(b1Σ g + ) metastable state in the positive column of a glow discharge in oxygen

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Literature cited

  1. 1.

    A. I. Maksimov and V. I. Svettsov, “Oxidating processes in a nonequilibrium low-pressure plasma,” Izv. Vyssh. Uchebn. Zaved., Khim. Tekhnol.,22, No. 10, 1167–1185 (1979).

  2. 2.

    V. K. Milinchuk, É. R. Klishpont, and S. Ya. Pshezhetskii, Macroradicals [in Russian], Khimiya, Moscow (1980).

  3. 3.

    A. I. Maksimov, A. F. Sergienko, and D. I. Slovetskii, “Gas temperature measurement in a glow discharge by a thermocouple method,” Fiz. Plazmy,4, No. 2, 347–351 (1978).

  4. 4.

    A. I. Maksimov, V. M. Menagarishvili, and V. V. Rybkin, “Analysis of electron-energy distributions, cross sections, and rate coefficients for processes involving electrons in an oxygen plasma,” Fiz. Plazmy,7, No. 2, 289–295 (1981).

  5. 5.

    J. T. Herron and H. J. Schiff, “A mass spectrometric study of normal oxygen and oxygen subjected to electrical discharge,” Can. J. Chem.,36, No. 5, 1159–1170 (1958).

  6. 6.

    S. N. Foner and R. L. Hudson, “Metastable oxygen molecules produced by electrical discharges,” J. Chem. Phys.,25, No. 3, 601–602 (1956).

  7. 7.

    S. J. Arnold and E. A. Ogryzlo, “Some reactions forming O2(1Σ g + ) in the upper atmosphere,” Can. J. Phys.,45, 2053–2061 (1967).

  8. 8.

    N. P. Penkin and O. D. Tsygir, “Effective excitation cross sections for 01 spectral lines in the collisions of electrons with oxygen atoms and molecules,” Opt. Spektrosk.,35, No. 3, 593–596 (1973).

  9. 9.

    P. S. Julienne and J. Davis, “Cascade and radiation trapping effects on atmospheric atomic oxygen emission excited by electron impact,” J. Geophys. Res.,81, No. 7, 1397–1403 (1976).

  10. 10.

    M. D. Costa, P. A. Zuliani, and J. M. Deckers, “Chemical reactions in glow discharge. Part 4. Production and removal of oxygen atoms in the dc glow discharge,” Can. J. Chem.,57, No. 5, 568–579 (1979).

  11. 11.

    M. Cacciatore, M. Capitelli, and M. Dilonardo, “Nonequilibrium vibrational population and dissociation rates of oxygen in electrical discharge: the role of atoms and of the recombination process,” Beitr. Plasmaphys.,18, No. 5, 279–299 (1978).

  12. 12.

    I. K. Kikoin (ed.), Tables of Physical Quantities (Handbook) [in Russian], Atomizdat, Moscow (1976).

  13. 13.

    R. Sh. Islamov, I. V. Kochetov, and V. G. Pevgov, Analysis of the Interactions of Electrons with Oxygen Molecules [in Russian], Moscow (1977), (Preprint No. 169/FIAN SSSR).

  14. 14.

    E. A. Koroleva and A. E. Khvorostovskaya, “Metastable-level deactivation processes in a glow discharge in oxygen,” Opt. Spektrosk.,33, No. 4, 627–630 (1972).

  15. 15.

    E. A. Koroleva and A. E. Khvorostovskaya, “Deactivation coefficients for O(1D) and O(1S) metastable atoms in a glow discharge in oxygen,” Opt. Spektrosk.,35, No. 1, 19–23 (1973).

  16. 16.

    K. Masek, T. Ruzicka, and L. Laska, “Electron gas in molecular oxygen discharge,” Czech. J. Phys.,27, No. 8, 888–898 (1977).

  17. 17.

    K. Smith, R. J. W. Henry, and P. G. Burke, “Calculation on the scattering of electrons by atomic systems with configurations 2p9,” Phys. Rev.,157, No. 1, 51–68 (1967).

  18. 18.

    A. E. Khvorostovskaya and V. A. Yankovskii, “The mechanism of formation of ozone in a glow discharge in molecular oxygen,” Opt. Spektrosk.,37, No. 1, 26–30 (1974).

  19. 19.

    D. E. Bursh and D. A. Gryvnak, “Strengths, widths, and shapes of the oxygen lines near 13,000 cm−1 (7620 Å),” Appl. Opt.,8, No. 7, 1493–1499 (1969).

  20. 20.

    S. Q. Lawton and A. V. Phelps, “Excitation of the b1Σ g + state of O2 by low energy electrons,” J. Chem. Phys.,69, No. 3, 1055–1068 (1978).

  21. 21.

    S. Trajmar, D. C. Cartwright, and W. Williams, “Differential and integral cross sections for the electron-impact excitation of thea 1Δg and b1Σ g + states of O2,” Phys. Rev. A,4, No. 4, 1482–1492 (1971).

  22. 22.

    R. I. Hall and S. Trajmar, “Scattering of 4.5 eV electrons by ground (x3Σ g + ) state and metastable (a 1Δg) oxygen molecules,” J. Phys. B: Atom. Mol. Phys.,8, No. 12, 293–296 (1975).

  23. 23.

    R. G. Derwent and B. A. Thrush, “Measurements on O2 1Δg and O2 1Σ g + in discharge flow systems,” Trans. Faraday Soc., No. 7, 2036–2043 (1971).

  24. 24.

    R. Atkinson and K. H. Welge, “Temperature dependence of O(1S) deactivation by CO2, O2, N2, and Ar,” J. Chem. Phys.,57, No. 9, 3689–3693 (1972).

  25. 25.

    R. A. Young and G. Black, “Excited-state formation and destruction in mixtures of atomic oxygen and nitrogen,” J. Chem. Phys.,44, No. 10, 3741–3751 (1966).

  26. 26.

    J. F. Noxon, “Optical emission from O(1D) and O2(b1Σ g + ) in ultraviolet photolysis of O and CO,” J. Chem. Phys.,52, No. 4, 1852–1873 (1970).

  27. 27.

    R. Gilpin, H. I. Schiff, and K. H. Welge, “Photodissociation of O2 in the Hartley band. Reaction of O(1D) and O2(b1Σ g + ) with O3 and O2,” J. Chem. Phys.,55, No. 3, 1087–1093 (1971).

  28. 28.

    T. G. Slanger and G. Black, “Interactions of O2b1Σ g + ) with O(3P) and O3,” J. Chem. Phys.,70, No. 7, 3434–3445 (1979).

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Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 37, No. 1, pp. 33–38, July, 1982.

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Maksimov, A.I., Rybkin, V.V. Formation and destruction of the O2(b1Σ g + ) metastable state in the positive column of a glow discharge in oxygen. J Appl Spectrosc 37, 756–760 (1982). https://doi.org/10.1007/BF00663823

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  • Oxygen
  • Analytical Chemistry
  • Molecular Structure
  • Metastable State
  • Glow Discharge