Organic onium salts (3–15) are prepared and their inclusion capacity towards solvent molecules is investigated. The crystal structure of the1·propanol·H2O clathrate ofN,N′-[5-tert-butyl-1,3-phenylenebis(methylene)]bis(quinuclidinium)dibromide (4) is reported and compared with the X-ray structures of related clathrates described earlier.
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H.-G. Löhr, H.-P. Josel, A. Engel, F. Vögtle, W. Schuh, and H. Puff,Chem. Ber. 117, 1487 (1984).
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Supplementary Data: Details of the crystal structure are available on request from the Fachinformationszentrum Energie-Physik-Mathematik, D-7517 Eggenstein, Leopoldshafen 2, by quoting the depository number CSD 50883, the names of the authors, and the journal citation.
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Josel, H., Löhr, H., Engel, A. et al. Clathrates of organic onium halides, V: preparation of new clathrates and structure of the 1-propanol inclusion of a bis-quinuclidinium salt. Journal of Inclusion Phenomena 3, 43–50 (1985). https://doi.org/10.1007/BF00658860
- X-ray analysis
- ammonium compounds
- phosphonium compounds
- quinuclidinium derivative