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Clathrates of organic onium halides, V: preparation of new clathrates and structure of the 1-propanol inclusion of a bis-quinuclidinium salt

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Abstract

Organic onium salts (3–15) are prepared and their inclusion capacity towards solvent molecules is investigated. The crystal structure of the1·propanol·H2O clathrate ofN,N′-[5-tert-butyl-1,3-phenylenebis(methylene)]bis(quinuclidinium)dibromide (4) is reported and compared with the X-ray structures of related clathrates described earlier.

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References

  1. 1.

    H.-G. Löhr, H.-P. Josel, A. Engel, F. Vögtle, W. Schuh, and H. Puff,Chem. Ber. 117, 1487 (1984).

  2. 2.

    F. Vögtle, H.-G. Löhr, H. Puff, and W. Schuh,Angew. Chem. 95, 425 (1983);Angew. Chem., Int. Ed. Engl. 22, 409 (1983);Angew. Chem. Suppl. 1983, 527–536.

  3. 3.

    H.-G. Löhr, F. Vögtle, W. Schuh, and H. Puff,J. Chem. Soc. Chem. Commun. 1983, 924.

  4. 4.

    H.-G. Löhr, F. Vögtle, W. Schuh, and H. Puff,J. Incl. Phenom. 1, 175 (1983).

  5. 5.

    P. Main, S. J. Fiske, S. E. Hull, L. Lessinger, G. Germain, J. P. Declerq, and M. M. Woolfson, MULTAN 80: A system of computer programs for the automatic solution of crystal structures from X-ray diffraction data, York, 1980.

  6. 6.

    G. M. Sheldrick, SHELX 76: Program for Crystal Structure Determination, Cambridge, 1976.

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Author information

Correspondence to Fritz Vögtle.

Additional information

Supplementary Data: Details of the crystal structure are available on request from the Fachinformationszentrum Energie-Physik-Mathematik, D-7517 Eggenstein, Leopoldshafen 2, by quoting the depository number CSD 50883, the names of the authors, and the journal citation.

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Josel, H., Löhr, H., Engel, A. et al. Clathrates of organic onium halides, V: preparation of new clathrates and structure of the 1-propanol inclusion of a bis-quinuclidinium salt. Journal of Inclusion Phenomena 3, 43–50 (1985). https://doi.org/10.1007/BF00658860

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Key words

  • Inclusion
  • clathrate
  • clathrand
  • host/guest
  • X-ray analysis
  • ammonium compounds
  • phosphonium compounds
  • quinuclidinium derivative