Core-shell composite polymer particle consisting of a hydrophilic core and hydrophobic shell was produced by the stepwise heterocoagulation of small cationic styrene-butyl acrylate-methacryloyoxyethyl trimethylammonium chloride terpolymer particles onto a large anionic methyl methacrylate-ethyl acrylate-methacrylic acid terpolymer particle (LP), which was proposed by the authors in 1990. In order to prepare a film from such a core-shell composite polymer emulsion, the shell content was controlled by changing the diameter of LP and by increasing the methacrylic acid content in LP.
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Okubo, M., Lu, Y. Preparation of heterogeneous film from core-shell composite polymer particles produced by the stepwise heterocoagulation method with heat treatment. Colloid Polym Sci 274, 1020–1024 (1996). https://doi.org/10.1007/BF00658366
- emulsion polymerization
- stepwise heterocoagulation
- heterogeneous structure