Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Excess molar volumes of 1-nonanol withn-heptane at 25, 35 and 45°C1

  • 45 Accesses

  • 10 Citations

Abstract

The excess molar volumes V m E at atmospheric pressure and at 25, 35 and 45°C for binary mixtures of 1-nonanol, with n-heptane have been obtained over the whole mole fraction range from densities measured with a vibrating-tube densimeter. The measurements at 25°C were extended to high dilution of 1-nonanol. The V m E are sigmoid for the three temperatures, with a small maximum at low mole fractions of the alkanol. The absolute values of V m E increase with temperature from 25 to 45°C.

This is a preview of subscription content, log in to check access.

References

  1. 1.

    L. A. K. Staveley and B. Spice,J. Chem. Soc. 406 (1952).

  2. 2.

    H. C. Van Ness, C. A. Soczek, and N. K. Kochar,J. Chem. Eng. Data. 12, 346 (1967).

  3. 3.

    I. Brown, W. Fock, and F. Smith,J. Chem. Thermodyn. 1, 273 (1969).

  4. 4.

    B. M. C. Vidyasagar Gupta, P. R. Naidu and M. V. P. Rao,J. Chem. Thermodyn. 8, 191 (1976).

  5. 5.

    A. J. Treszczanowicz and G. C. Benson,J. Chem. Thermodyn. 9, 1189 (1977).

  6. 6.

    A. J. Treszczanowicz and G. C. Benson,J. Chem. Thermodyn. 10, 967 (1978).

  7. 7.

    A. J. Treszczanowicz and G. C. Benson,J. Chem. Thermodyn. 12, 173 (1980).

  8. 8.

    A. J. Treszczanowicz, O. Kiyohara, and G. C. Benson,J. Chem. Thermodyn. 13, 253 (1981).

  9. 9.

    C. Berro, M. Rogalski, and A. Peneloux,J. Chem. Eng. Data. 27, 352 (1982).

  10. 10.

    M. K. Kumaran and G. C. Benson,J. Chem. Thermodyn. 15, 245 (1983).

  11. 11.

    R. Bravo, M. Pintos, M. C. Baluja, M. I. Paz Andrade, G. Roux-Desgranges, and J.-P. E. Grolier,J. Chem. Thermodyn. 16, 73 (1984).

  12. 12.

    A. J. Treszczanowicz and G. C. Benson,J. Chem. Thermodyn. 16, 237 (1984).

  13. 13.

    K. N. Marsh and C. Burfitt,J. Chem. Thermodyn. 7, 955 (1975).

  14. 14.

    S. A. Wieczorek,J. Chem. Thermodyn. 16, 115 (1984).

  15. 15.

    J. T. Sipowska and S. A. Wieczorek,J. Chem. Thermodyn. 17, 703 (1985).

  16. 16.

    J. A. Gates, R. H. Wood, J. C. Cobos, C. Casanova, A. H. Roux, G. Roux-Desgranges, and J.-P. E. Grolier,Fluid Phase Equil. 27, 137 (1986).

  17. 17.

    D. Wagner and A. Heintz,J. Chem. Eng. Data 31, 483 (1986).

  18. 18.

    A. Heintz, B. Schmittecker, D. Wagner, and R. N. Lichtenthaler,J. Chem. Eng. Data 31, 487 (1986).

  19. 19.

    I. García de la Fuente, J. F. Rodríguez, J. A. González, J. C. Cobos and C. Casanova,J. Chem. Thermodyn. 24, 23 (1992).

  20. 20.

    IUPAC Commission on Atomic Weights and Isotopic Abundances 1985,Pure Appl. Chem. 58, 1677 (1986).

  21. 21.

    J. A. Riddick, W. B. Bunger, and T. K. Sakano,Organic Solvents, Techniques of Chemistry, Vol II, A. Weissberger, ed. (Wiley, New York, 1986).

  22. 22.

    TRC Thermodynamics Tables: Hydrocarbons, Thermodynamics Research Center (A&M University, College Station, Texas, 1986).

  23. 23.

    R. Tanaka,J. Colloid Interface Sci. 122, 220 (1986).

  24. 24.

    R. Tanaka, S. Toyama, and S. Murakami,J. Chem. Thermodyn. 18, 63 (1986).

  25. 25.

    R. Tanaka,J. Chem. Eng. Data 32, 176 (1987).

  26. 26.

    J. T. Sipowska and S. A. Wieczorek,J. Chem. Thermodyn. 20, 333 (1988).

  27. 27.

    R. Tanaka, T. Nakamichi, and S. Murakami,J. Solution. Chem. 14, 795 (1985).

  28. 28.

    M. Díaz Peña, and G. Tardajos,J. Chem. Thermodyn. 10, 19 (1978).

  29. 29.

    O. Kratky, H. Leopold, and H. Stabinger,Z. Angew. Phys. 27, 273 (1969).

  30. 30.

    H. Leopold,Elektron. 19, 297 (1970).

  31. 31.

    H. Leopold,Elektron. 19, 411 (1970).

  32. 32.

    A. J. Treszczanowicz, O. Kiyohara, and G. C. Benson.,Bull. Acad. Polon. Sci., Ser. Sci. Chim. 29, 103 (1981).

Download references

Author information

Correspondence to I. García de la Fuente.

Additional information

Communicated in part at the 4th International Conference on Thermodynamics of Solution of Non-Electrolytes, Santiago de Compostela, Spain (1989).

Rights and permissions

Reprints and Permissions

About this article

Cite this article

de la Fuente, I.G., Rodríguez, J.F., González, J.A. et al. Excess molar volumes of 1-nonanol withn-heptane at 25, 35 and 45°C1 . J Solution Chem 21, 425–431 (1992). https://doi.org/10.1007/BF00649696

Download citation

Key words

  • Excess molar volume
  • 1-nonanol
  • n-heptane