The conductance of cesium nitrate in water-THF mixtures has been measured at 25°C. The salt was found associated in the whole range studied from pure water to 70% THF mixture. The experimental data were reduced to the Rasaiah and Friedman Gurney parameterh +-/kT. It was found that for these systems solvation effects systematically reinforce the electrostatic attraction.
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Bury, R., Justice, J.C. Conductance of cesium nitrate in water-tetrahydrofuran mixtures at 25°C. J Solution Chem 6, 349–355 (1977). https://doi.org/10.1007/BF00647049
- Cesium nitrate
- water-THF mixtures
- association constant
- Gurney parameters