The excess volume of mixing of some electron-donating aromatic hydrocarbons like benzene, toluene,p-xylene, and mesitylene with an electronaccepting liquid 1,2,4-trichlorobenzene have been measured at 30°C. The results indicate that the interaction between the components increases as the electron-donating power of the hydrocarbons increases. The V m e values are related to the ionization potentials of the hydrocarbons.
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W. A. Duncan, J. P. Sheridan, and F. W. Swinton,Trans. Faraday Soc. 62, 1090 (1966).
D. K. Agarwal and S. Agarwal,J. Indian Chem. Soc., in press.
R. Gopal and S. Agarwal,J. Chem. Thermodyn. 8, 189 (1976).
J. Timmermans,Physico-chemical Constants of Pure Organic Compounds (Elsevier Publishing Co., New York, 1970).
D. B. Myers and R. L. Scott.,Ind. Eng. Chem. 55, 43 (1963).
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Agarwal, S. Excess volume of mixing of some electron-donating hydrocarbons with an electron-accepting liquid 1,2,4-trichlorobenzene. J Solution Chem 7, 795–798 (1978). https://doi.org/10.1007/BF00643583
- Excess volume