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Excess volume of mixing of some electron-donating hydrocarbons with an electron-accepting liquid 1,2,4-trichlorobenzene

Abstract

The excess volume of mixing of some electron-donating aromatic hydrocarbons like benzene, toluene,p-xylene, and mesitylene with an electronaccepting liquid 1,2,4-trichlorobenzene have been measured at 30°C. The results indicate that the interaction between the components increases as the electron-donating power of the hydrocarbons increases. The V m e values are related to the ionization potentials of the hydrocarbons.

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Agarwal, S. Excess volume of mixing of some electron-donating hydrocarbons with an electron-accepting liquid 1,2,4-trichlorobenzene. J Solution Chem 7, 795–798 (1978). https://doi.org/10.1007/BF00643583

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Key words

  • Excess volume
  • trichlorobenzene
  • benzene
  • toluene
  • p-xylene
  • mesitylene